Synthesis of Six-Membered Carbo-/Heterocycles via Cascade Reaction of Alkynes and Diazo Compounds
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A novel approach toward diverse six-membered carbo-/heterocycles has been developed using diazo compounds and alkyne-substituted malonates as the suitable substrates. The polyfunctionalized cyclohexenes, tetrahydropyridines, and dihydropyrans have been prepared in moderate to high yield under mild reaction conditions. Importantly, the ligand plays a significant role in this copper-catalyzed protocol.
创建时间：
2017-04-27
