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Arene−Chromium Tricarbonyl Complexes in the Pauson−Khand Reaction

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https://figshare.com/articles/dataset/Arene_Chromium_Tricarbonyl_Complexes_in_the_Pauson_Khand_Reaction/3252832
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资源简介:
We show the use of arene−chromium tricarbonyl complexes in intra- and intermolecular Pauson−Khand reactions. Both styrene and ethynylbenzene complexes react with alkynes and olefins. The synthesis of enynes connected through chromium-complexed aromatic rings is developed. The intramolecular Pauson−Khand reaction occurs in a totally diastereoselective manner.
创建时间:
2016-05-05
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