Synthesis of Oligoparaphenylene-Derived Nanohoops Employing an Anthracene Photodimerization–Cycloreversion Strategy
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The century-old yet synthetically underexplored anthracene photodimerization–cycloreversion reactions have been employed as the key steps to access highly strained aromatic hydrocarbons. Herein we report the chemical syntheses of oligoparaphenylene-derived nanohoops in five steps or less featuring a rigid dianthracene synthon. The newly synthesized nanohoops display intriguing experimental and computational properties.
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2016-08-31
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