General Design Strategy for Aromatic Ketone-Based Single-Component Dual-Emissive Materials

Materials with both fluorescence and room-temperature phosphorescence (RTP) can be useful in the field of optoelectronics. Here we present a general strategy, taking advantage of carbonyl compounds, which have been known to possess efficient intersystem crossing with high triplet state yield, as well as a strongly fluorescent intramolecular charge-transfer (ICT) state, to produce materials with both fluorescence and RTP at the same time, or dual-emission. In the presented model systems, in order to generate a suitable ICT state, Lewis acid binding to aromatic ketone derivatives has been proved to be a viable method. We have selected AlCl3, BCl3, BF3, and GdCl3 as binding Lewis acids, in that they exhibit sufficiently strong binding affinity toward the aromatic ketone derivatives to afford stable complexes and yet do not possess low-lying electronic transitions vs the ligands. We have successfully observed dual-emission from these designed complexes in polymers, which act to suppress competitive thermal decay at room temperature. One of the complexes is particularly interesting as it is dual-emissive in the crystalline state. Single-crystal XRD reveals that the molecule forms multiple hydrogen bonds with its neighbors in crystals, which may significantly enhance the rigidity of the environment.