Recognition-Mediated Facilitation of a Disfavored Diels−Alder Reaction
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https://figshare.com/articles/dataset/Recognition-Mediated_Facilitation_of_a_Disfavored_Diels_Alder_Reaction/3760761
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资源简介:
The rational design of a system which is capable of accelerating and facilitating a thermodynamically disfavored Diels−Alder cycloaddition
between a furan and a maleimide is presented. The origins of the acceleration and facilitation of the cycloaddition reaction are traced by
kinetic studiesallied to results from 1H NMR spectroscopy and X-ray crystallographyto the formation of strong intramolecular hydrogen
bonds in the cycloadduct.
创建时间:
2016-08-26



