A Planar Water Tetramer with Tetrahedrally Coordinated Water Embedded in a Hydrogen Bonding Network of [Tc<sub>4</sub>(CO)<sub>12</sub>-(μ<sub>3</sub>-OH)<sub>4</sub>·4H<sub>2</sub>O]
收藏NIAID Data Ecosystem2026-03-06 收录
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A virtually planar water tetramer in which the water molecules are virtually tetrahedrally coordinated could be realized in the solid in a three-dimensional network of [Tc4(CO)12-(μ3−OH)4·4H2O]. The network could be produced by cocrystallization of the new cubane-like cluster [Tc(CO)3-(μ3-OH)]4 and water as a complementary component. The amphiphilic behavior of cluster and water results in a highly ordered three-dimensional network. The complementary components, the water tetramer and the cubic cluster, independently of one another form two interpenetrating tetragonal lattice networks held together exclusively by hydrogen bonds.
创建时间：
2016-05-05
