Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI‑D Analysis of a Novel Diaryltellurium Acetimidate
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https://figshare.com/articles/dataset/Oxygen_Transfer_from_an_Intramolecularly_Coordinated_Diaryltellurium_Oxide_to_Acetonitrile_Formation_and_Combined_AIM_and_ELI_D_Analysis_of_a_Novel_Diaryltellurium_Acetimidate/2267911
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资源简介:
The reaction of the intramolecularly
coordinated diaryltellurium(IV)
oxide (8-Me2NC10H6)2TeO
with acetonitrile proceeds with oxygen transfer and gives rise to
the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate
(8-Me2NC10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric
acid affords acetamide and the previously known diarylhydroxytelluronium(IV)
chloride [(8-Me2NC10H6)2Te(OH)]Cl.
创建时间:
2014-08-06



