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Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI‑D Analysis of a Novel Diaryltellurium Acetimidate

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NIAID Data Ecosystem2026-03-08 收录
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The reaction of the intramolecularly coordinated diaryltellurium­(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium­(IV) acetimidate (8-Me2NC10H6)2TeNC­(O)­CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium­(IV) chloride [(8-Me2NC10H6)2Te­(OH)]­Cl.

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2014-08-06
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