Palladium-Catalyzed Coupling of Haloalkynes with Allyl Acetate: A Regio- and Stereoselective Synthesis of (<i>Z</i>)-β-Haloenol Acetates
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A Pd-catalyzed coupling of haloalkynes with allyl acetate has been reported, providing a convenient method for the stereoselective synthesis of (Z)-β-haloenol acetates in good yields. The synthetic utility of this method is demonstrated by the formation of functionalized enol acetates via the Suzuki–Miyaura or Sonogashira coupling of the resulting (Z)-β-haloenol acetate products.
创建时间:
2011-08-05



