Synthesis and Single-Crystal X-ray Diffraction Examination of a Structurally Homologous Series of Tetracoordinate Heteroleptic Anionic Lanthanide Complexes: Ln{N[Si(CH<sub>3</sub>)<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>Si(CH<sub>3</sub>)<sub>2</sub>]}<sub>3</sub>(μ-Cl)Li(L)<sub>3</sub> [Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb; (L)<sub>3</sub> = (THF)<sub>3</sub>, (Et<sub>2</sub>O)<sub>3</sub>, (THF)<sub>2</sub>(Et<sub>2</sub>O)]
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https://figshare.com/articles/dataset/Synthesis_and_Single-Crystal_X-ray_Diffraction_Examination_of_a_Structurally_Homologous_Series_of_Tetracoordinate_Heteroleptic_Anionic_Lanthanide_Complexes_Ln_N_Si_CH_sub_3_sub_sub_2_sub_CH_sub_2_sub_CH_sub_2_sub_Si_CH_sub_3_sub_sub_2_sub_sub_3_sub_-Cl_Li/3626817数据链接链接失效反馈
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资源简介：
Anhydrous lanthanide(III) chlorides (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb) react with 3 equiv of lithium 2,2,5,5-tetramethyl-2,5-disila-1-azacyclopentanide, in THF or Et2O to afford the monomeric four-coordinate heteroleptic ate complexes (Ln = Sm (1), Eu (2), Gd (3), Tb (4), Dy (5), Ho (6), Er (7), Tm (8), Yb (9)), whose solid-state structures were determined by the single-crystal X-ray diffraction technique. All complexes additionally were characterized by melting point determination, elemental analyses, and mass spectrometry.
创建时间：
2016-08-18
