Three-Component, Stereoselective Palladium-Catalyzed Synthesis of Functionalized Bicyclopentanoids
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https://figshare.com/articles/dataset/Three_Component_Stereoselective_Palladium_Catalyzed_Synthesis_of_Functionalized_Bicyclopentanoids/3316363
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资源简介:
1,5-Cyclooctadiene can be stereoselectively transformed into a substituted bicyclo[3.3.0]octane ring system under palladium catalysis with
concomitant formation of three carbon−carbon bonds. Reaction with an aryl iodide or triflate and malonate gives an exo-endo product, while
the reaction with a malonate in the presence of oxygen affords a bis-endo adduct.
创建时间:
2004-11-11



