Enantioselective C–C Bond Formation during the Oxidation of 5‑Phenylpent-2-enyl Carboxylates with Hypervalent Iodine(III)
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https://figshare.com/articles/dataset/Enantioselective_C_C_Bond_Formation_during_the_Oxidation_of_5_Phenylpent-2-enyl_Carboxylates_with_Hypervalent_Iodine_III_/5071750
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资源简介：
The
oxidation of (5-acyloxypent-3-enyl)benzene with hypervalent
iodine(III) afforded 2-oxy-1-(oxymethyl)tetrahydronaphthalene under
metal-free conditions. The acyloxy group may nucleophilically participate
in the oxidative cyclization. A lactate-based chiral hypervalent iodine
afforded an enantioselective variant of oxyarylation with up to 89%
ee.
创建时间：
2017-06-03
