Total Syntheses of Sesterpenic Acids: Refuted (±)-Bilosespenes A and B
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https://figshare.com/articles/dataset/Total_Syntheses_of_Sesterpenic_Acids_Refuted_Bilosespenes_A_and_B/3358654
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资源简介：
The total syntheses of racemic sesterpenic acids 1 and 2 have been accomplished from creosol (6) in 12 and 13 steps, respectively. Intramolecular
Diels−Alder reaction of masked o-benzoquinone 7 generated from 6 and allyl alcohol, stereoselective addition of alkenylcerium(III) chloride 8
to ketone 5, and anionic oxy-Cope rearrangement of dienol 4 are the key steps.
创建时间：
2016-05-07
