Solvent-Dependent Self-Assembly of an Oxalato-Based Three-Dimensional Magnet Exhibiting a Novel Architecture
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https://figshare.com/articles/dataset/Solvent-Dependent_Self-Assembly_of_an_Oxalato-Based_Three-Dimensional_Magnet_Exhibiting_a_Novel_Architecture/3473732
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资源简介：
The
old but evergreen family of bimetallic oxalates still offers innovative
and interesting results. When (Me4N)3[Cr(ox)3]·3H2O is reacted with MnII ions
in a nonaqueous solvent, a novel three-dimensional magnet of the formula
[N(CH3)4]6[Mn3Cr4(ox)12]·6CH3OH is obtained instead of
the one-dimensional compound obtained in water. This new material
exhibits an unprecedented stoichiometry with a binodal (3,4) net topology
and the highest critical temperature (TC = 7 K) observed so far in a manganese–chromium oxalate based
magnet.
创建时间：
2016-07-12
