Structural Variability in Neptunium(V) Oxalate Compounds: Synthesis and Structural Characterization of Na<sub>2</sub>NpO<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)OH·H<sub>2</sub>O
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Reaction of a 237Np(V) stock solution in the presence of oxalic acid, calcium chloride, and sodium hydroxide under hydrothermal conditions produces single crystals of a neptunium(V) oxalate, Na2NpO2(C2O4)OH·H2O. The structure consists of one-dimensional chains running down the a axis and is the first example of a neptunium(V) oxalate compound containing hydroxide anions.
创建时间:
2004-10-04



