A Two-Step, Stereoselective Synthesis of Nine- and Ten-Membered Carbocycles from Phthalates
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https://figshare.com/articles/dataset/A_Two_Step_Stereoselective_Synthesis_of_Nine_and_Ten_Membered_Carbocycles_from_Phthalates/2170825
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资源简介：
A two-step, stereoselective procedure for the synthesis of nine- and ten-membered carbocycles from readily available phthalates is described. A variety of dialkyl phthalates have been transformed into [6,n]-fused bicyclo systems (n = 5, 6, 7) by a dearomatization/cyclization process and then converted into cyclonona- and cyclodecadienes through a bond cleavage reaction, whereby both processes are promoted by alkaline metals in THF.
创建时间：
2016-02-13
