A series of compounds has been made containing quadruply bonded Re2(hpp)4X2 species (hpp = the anion of 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2a]pyrimidine), where X is CF3SO3 (1), CF3CO2 (2), and F (3)
Here we report the data collected by the conventional spectroscopy. The raw data generalized from the instruments have been uploaded. And they have been restored in .txt and .xlsx files.
Into the metalloligand Cr[N(o-(NCH2P(iPr)2)C6H4)3] (1, CrL) was inserted a second chromium atom to generate the dichromium complex Cr2L (2), which is a homobimetallic analogue of the known MCrL co
Four-electron oxidation of the quadruply bonded W2(II,II) compound W2(2,2′-dipyridylamide)4, 1, results in the formation of a novel, diamagnetic ditungsten terminal oxo compound [W2O(2,2′-dipyridylami