Synthesis of (±)-<i>epi</i>-Stegobinone Utilizing Silacyclopropanes as Synthetic Intermediates
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The synthesis of (±)-1‘-epi-stegobinone has been accomplished in ten steps and 17% overall yield from a recently reported silacyclopropane-derived diol. All stereocenters of the final product were established relative to the stereochemistry of the initial silacyclopropane. This synthesis represents the first time silacyclopropane reactivity has been employed in a target-directed synthesis.
创建时间：
2007-02-02
