Enantioselective Total Syntheses of Omuralide, 7-<i>epi</i>-Omuralide, and (+)-Lactacystin
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An alkylidene carbene 1,5-CH insertion has been used as a key step in an enantioselective total syntheses of omuralide, its C7-epimer, and (+)-lactacystin. An additional noteworthy feature of the synthesis is the use of a novel oxidative deprotection procedure, utilizing DMDO, for the conversion of a late-stage benzylidene acetal into a primary alcohol and a secondary benzoate ester.
创建时间：
2016-06-03
