Assembly of [MnII2MnIII2] S = 9 Clusters via Azido Bridges: a New Single-Chain Magnet
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In the present work, we report a new manganese single-chain magnet built from tetranuclear MnII2MnIII2 mixed-valence units linked by end-on azido and oximato bridges. All of the intra- and intercluster interactions involve end-on azido bridges, resulting in one ferromagnetic chain of ferromagnetic clusters with local ground state S = 9.
创建时间:
2016-02-23



