Ring-Opening Reactions of Nonactivated Aziridines Catalyzed by Tris(pentafluorophenyl)borane
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https://figshare.com/articles/dataset/Ring-Opening_Reactions_of_Nonactivated_Aziridines_Catalyzed_by_Tris_pentafluorophenyl_borane/3699300
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资源简介：
The ring-opening reactions of nonactivated aziridines with amine nucleophiles are efficiently
catalyzed by tris(pentafluorophenyl)borane leading to derivatives of trans-1,2-diamines in high
yields. A mechanistic investigation of the reaction suggests that in situ formed [(C6F5)3B(OH2)]·H2O catalyzes the opening through a Brønsted acid manifold.
创建时间：
2016-08-19
