Ring-Opening Reactions of Nonactivated Aziridines Catalyzed by Tris(pentafluorophenyl)borane
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
The ring-opening reactions of nonactivated aziridines with amine nucleophiles are efficiently catalyzed by tris(pentafluorophenyl)borane leading to derivatives of trans-1,2-diamines in high yields. A mechanistic investigation of the reaction suggests that in situ formed [(C6F5)3B(OH2)]·H2O catalyzes the opening through a Brønsted acid manifold.
创建时间：
2016-08-19
