Competition between sp3‑C–N vs sp3‑C–F Reductive Elimination from PdIV Complexes
收藏Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Competition_between_sp_sup_3_sup_C_N_vs_sp_sup_3_sup_C_F_Reductive_Elimination_from_Pd_sup_IV_sup_Complexes/2313622
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This communication describes the design of a model system that allows direct investigation of competing sp3-C–N and sp3-C–F bond-forming reductive elimination from a PdIV fluoro sulfonamide complex. The reductive elimination selectivity varies dramatically as a function of reaction additives. A mechanism is proposed that provides a rationale for these effects.
创建时间：
2016-02-17
