Facile Peripheral Modification of N-Confused Porphyrin
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https://figshare.com/articles/dataset/Facile_Peripheral_Modification_of_N_Confused_Porphyrin/3242890
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资源简介:
An improved methodology for the N-alkylation of the
porphyrin isomer N-confused porphyrin is presented. The
combination of polar solvent conditions and the use of the
base Cs2CO3 affords externally modified products in high
yield without separation difficulties and without the use of
large excesses of alkylating reagent. The further transformation and metalation of these products provides opportunities
for the construction of metalloenzyme model complexes,
peptide adducts, and chromophore assemblies.
创建时间:
2006-01-20



