A Convenient Synthesis of Tetrabenzo[<i>de,hi,mn,qr</i>]naphthacene from Readily Available 1,2-Di(phenanthren-4-yl)ethyne

We report here a convenient synthesis of tetrabenzo[de,hi,mn,qr]naphthacenes from 1,2-di(phenanthren-4-yl)ethynes through initial Bro̷nsted acid-catalyzed hydroarylation, followed by FeCl3-oxidative coupling reactions. This new method is applicable to tetrabenzo[de,hi,mn,qr]naphthacenes bearing various alkyl substituents.