Ruthenium η4‑Trimethylenemethane Complexes Containing Tripodal Phosphanomethylamine Ligands
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Ruthenium η4-trimethylenemethane complexes containing two different tridentate phosphine ligands have been synthesized. The formation of the complexes using [Ru(η4-COD)(η3-CH2CMeCH2)2] as the metal precursor occurred via elimination of isobutene. An intermediate species has been isolated in which the ligand coordinates with only two phosphorus atoms. Furthermore, protonation of the trimethylenemethane ligand gave rise to a cationic methylallyl complex.
创建时间：
2016-02-20
