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Through-space Electrostatic Interaction between the Electron-donating 1,3-Diphosphacyclobutane-2,4-diyl Units

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Through_space_Electrostatic_Interaction_between_the_Electron_donating_1_3_Diphosphacyclobutane_2_4_diyl_Units/2398774
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Catenation of stable 1,3-diphopsphacyclobutane-2,4-diyl units with biphenyl-, diphenyl ether-, and diphenylmethane-based bridging groups were utilized for evaluation of the distinct through-space interaction between the electron-donating P-heterocyclic biradical chromophores. Structural properties of the oligo(biradicals), characterized by X-ray crystallography and DFT calculation, suggest a possible distance between the biradical units for the through-space interaction.
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2016-02-19
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