Bicyclic Bridgehead Phosphoramidite (Briphos) Ligands with Tunable π‑Acceptor Ability and Catalytic Activity in the Rhodium-Catalyzed Conjugate Additions
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https://figshare.com/articles/dataset/Bicyclic_Bridgehead_Phosphoramidite_Briphos_Ligands_with_Tunable_Acceptor_Ability_and_Catalytic_Activity_in_the_Rhodium_Catalyzed_Conjugate_Additions/2244412
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资源简介：
A new type of bicyclic bridgehead
phosphoramidites (briphos) is
reported, where the geometrical constraints significantly enhance
the π-acceptor ability compared with its monocyclic analogs.
The briphos is shown to be highly efficient and tunable for Rh(I)-catalyzed
conjugate additions of aryl boronic acids to α,β-unsaturated
ketones and N-tosyl ketimines.
创建时间：
2016-02-16
