A Brønsted Acid Catalyst for the Enantioselective Protonation Reaction

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A Brønsted Acid Catalyst for the Enantioselective Protonation Reaction

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2016-02-27

Catalytic Asymmetric Synthesis of Chiral Covalent Organic Frameworks from Prochiral Monomers for Heterogeneous Asymmetric Catalysis

共价有机框架

不对称催化

Direct synthesis, postsynthetic modification, and chiral induction have been recognized as three powerful methods to synthesize chiral covalent organic frameworks (CCOFs). However, catalytic asymmetri

Figshare2020-09-17 更新70

Enantiodivergent Synthesis of Tertiary α‑Aryl 1‑Indanones: Evidence Toward Disparate Mechanisms in the Palladium-Catalyzed Decarboxylative Asymmetric Protonation

不对称催化

立体选择性合成

Herein, we describe a study into the scope and origin of an enantiodivergent effect in the palladium-catalyzed decarboxylative asymmetric protonation. By switching the achiral proton source, both enan

NIAID Data Ecosystem50

Highly Enantioselective Organocatalytic Trifluoromethyl Carbinol SynthesisA Caveat on Reaction Times and Product Isolation

不对称催化

手性醇合成

Aldol reactions with trifluoroacetophenones as acceptors yield chiral α-aryl, α-trifluoromethyl tertiary alcohols, valuable intermediates in organic synthesis. Of the various organocatalysts examined,

Figshare2016-02-20 更新20

Catalytic Asymmetric Diamination of Styrenes

不对称催化

苯乙烯二胺化

An enantioselective catalytic vicinal diamination of styrenes is reported, which proceeds under entirely intermolecular reaction control. It relies on a chirally modified aryliodine(I) catalyst and p

NIAID Data Ecosystem50

Synthesis of Enantiomerically Pure P-Stereogenic Diphosphacrowns and Their Palladium Complexes

手性配体合成

不对称催化

A practical synthetic route for enantiomerically pure P-stereogenic diphosphacrowns was developed by using a P-stereogenic bisphosphine as a chiral building block. Their molecular structures were conf

NIAID Data Ecosystem30

A Brønsted Acid Catalyst for the Enantioselective Protonation Reaction

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