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Total Synthesis of (+)-Przewalskin B

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NIAID Data Ecosystem2026-03-07 收录
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An efficient strategy for the total synthesis of (+)-przewalskin B is reported. The key steps feature an intermolecular SN2′ substitution of iodoallylic phosphate with organocupper reagent, a diastereoselective organocatalytic aldol cyclization, as well as a Rh2(OAc)4-mediated intramolecular carbene insertion to the tertiary C–H bond.

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2011-08-19
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