Materials Data on AgO2 by Materials Project

AgO2 crystallizes in the tetragonal I4_1/a space group. The structure is two-dimensional and consists of four AgO2 sheets oriented in the (0, 0, 1) direction. there are two inequivalent Ag sites. In the first Ag site, Ag is bonded in a rectangular see-saw-like geometry to four equivalent O atoms. All Ag–O bond lengths are 2.24 Å. In the second Ag site, Ag is bonded in a rectangular see-saw-like geometry to four equivalent O atoms. All Ag–O bond lengths are 2.23 Å. O is bonded in a trigonal planar geometry to two Ag and one O atom. The O–O bond length is 1.39 Å.

二氧化银（AgO₂）结晶于四方晶系I4₁/a空间群。该结构为二维结构，包含四张沿(0, 0, 1)方向排布的AgO₂片层。体系中存在两种不等价的银（Ag）位点：第一种Ag位点中，银原子以矩形跷跷板型配位几何与四个等价的氧原子成键，所有Ag-O键长均为2.24埃；第二种Ag位点中，银原子同样以矩形跷跷板型配位几何与四个等价的氧原子成键，所有Ag-O键长均为2.23埃。氧原子以平面三角形配位几何与两个银原子及一个氧原子成键，其O-O键长为1.39埃。