Synthesis and Isolation of Thorium Dinitrogen Complexes: 5f Orbital Matters

Thorium–dinitrogen complexes, long proposed as
critical
intermediates for actinide-mediated dinitrogen activation and bond
cleavage, have not been isolated. In this work, three heterobimetallic
[Cr]–N2–[Th] complexes featuring a Th–N2 moiety were synthesized via a metathesis reaction between
a chromium(0) dinitrogen precursor and Th(IV) chloride derivatives.
X-ray crystallographic analysis unambiguously confirmed their heterobimetallic
[Cr]–N2–[Th] bridging geometry. Density functional
theory (DFT) calculations revealed non-negligible 5f orbital contributions
to the Th–N bonding interactions.