five

Asymmetric Synthesis of the Core Structure of Leucosceptroids A–D

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Asymmetric_Synthesis_of_the_Core_Structure_of_Leucosceptroids_A_D/2625452
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The asymmetric synthesis of the core structure of leucosceptroids A–D has been achieved. The key steps of the synthesis includes the formation of the cis-2,5-disubstituted THF ring by TPAP catalytic oxidative cyclization followed by a highly diastereoselective intramolecular Diels–Alder reaction to fashion the fused tricyclic hydrindane ring system.
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2016-02-23
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