Branched Phospha[7]triangulanes
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
A highly strained, thermally stable (up to 150 °C) branched phospha[7]triangulane was synthesized from the second-generation bicyclopropylidene and transient phosphinidene [Ph−PW(CO)5], followed by demetalation in refluxing xylene. Bulkier transient CuCl−alkene-complexed phosphinidene gave 2-phosphabicyclo-[3.2.0]hept-1(5)-ene as an additional product. The “outer sphere” spirocyclopropanes provide a stabilizing factor for both of these novel compounds.
创建时间：
2004-03-17
