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Axial Donating Ligands: A New Strategy for Late Transition Metal Olefin Polymerization Catalysis

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https://figshare.com/articles/dataset/Axial_Donating_Ligands_A_New_Strategy_for_Late_Transition_Metal_Olefin_Polymerization_Catalysis/2933332 数据链接链接失效反馈

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Axial Donating Ligands: A New Strategy for Late Transition Metal Olefin Polymerization Catalysis

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创建时间：

2008-06-18

烯烃聚合

金属配合物

Cyclopentadienyl ligands functionalized by quinoline or N,N-dimethylaniline have an ideal and rigid geometry for the formation of half-sandwich compounds. As a result, stable chromium(III) complexes 5

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Chiral Naphthyl-α-diimine Nickel(II) Catalysts Bearing sec -Phenethyl Groups: Chain-Walking Polymerization of Ethylene at High Temperature and Stereoselective Polymerization of Methyl Methacrylate at Low Temperature

烯烃聚合

立体选择性聚合

A series of new naphthyl-α-diimine nickel(II) complexes, {bis[N,N′-(1-naphthyl)imino]-1,2-dimethylethane}dibromonickel (2a), {bis[N,N′-(2-methyl-1-naphthyl)imino]-1,2-dimethylethane}dibromonick

NIAID Data Ecosystem40

The New Tridentate Ligand CpSiNSiCp and Its Zirconium Complexes: Incorporation of Two Bridged Constrained-Geometry Units into One Molecule

烯烃聚合

约束几何催化剂

The new tridentate ligand CpSiNSiCp and its zirconium complexes have been prepared. These zirconium complexes, containing two constrained-geometry units that are linked together via the N−Zr bond in e

NIAID Data Ecosystem40

Synthesis of Half-Titanocenes Containing Phenoxy-imine Ligands and Their Use as Catalysts for Olefin Polymerization

烯烃聚合

金属茂催化剂

Various half-titanocenes containing phenoxy-imine ligands of the type Cp‘TiCl2[O-2-R1-6-(R2NCH)C6H3] [Cp‘ = Cp* (C5Me5) and R1, R2 = Me, 2,6-iPr2C6H3 (1); tBu, 2,6-iPr2C6H3 (2); Me, tBu (3); tBu, tBu

NIAID Data Ecosystem40

Dialkyl and Methyl-Alkyl Zirconocenes: Synthesis and Characterization of Zirconocene-Alkyls That Model the Polymeryl Chain in Alkene Polymerizations

金属茂催化剂

烯烃聚合

Zirconocene precatalysts with sterically bulky alkyl groups were designed as model systems for the propagating species in zirconocene-catalyzed alkene polymerization. Specialty alkyllithium reagents L

NIAID Data Ecosystem40

Axial Donating Ligands: A New Strategy for Late Transition Metal Olefin Polymerization Catalysis

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