Bonding and Reactivity in the Electronically Unsaturated Hydrogen-Bridged Dimer [Ru<sub>3</sub>(CO)<sub>8</sub>(μ<sub>3</sub>-CMe)(μ-H)<sub>2</sub>(μ<sub>3</sub>-H)]<sub>2</sub>
收藏NIAID Data Ecosystem2026-03-07 收录
数据链接：
官方服务：
资源简介：
The electronically unsaturated complex [Ru3(CO)8(μ3-CMe)(μ-H)2(μ3-H)]2 (1), viewed as a dimer of the 46-electron fragment Ru3(CO)8(μ3-CMe)(μ-H)3, is held together by delocalized bonding involving two triply bridging hydride ligands. Compound 1 exhibits a dynamic activity in solution that equilibrates two of the three types of hydride ligands. Compound 1 reacts with 1,1-bis(diphenylphosphino)methane to form the macrocyclic complex [Ru3(CO)7(μ3-CMe)(μ-H)3]2(μ-dppm)2 (3).
创建时间：
2012-01-09
