Hydroxyphosphinylation Reaction of 3‑Cyclopropylideneprop-2-en-1-ones via C–P σ‑Bond Cleavage
收藏数据链接：
官方服务：
资源简介：
An unexpected hydroxyphosphinylation of 3-cyclopropylideneprop-2-en-1-ones with phosphines has been observed. This method provides a unique regio- and stereoselective synthesis of highly functionalized 1-dialkylphinyl-3-oxo-(1Z)-alkenyl cyclopropanols with important potentials. The reaction displays an unusual mechanistic featurea highly selective cleavage of C–P σ bonds in phosphines.
创建时间：
2016-02-19
