Conversion of Propargyl Alcohols to Chloroallenes and Arylalkynes Using the TiCl<sub>4</sub>/R<sub>3</sub>N Reagent System
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Whereas the reaction of certain propargyl alcohols with TiCl4 in the presence of tertiary alkylamines gives the corresponding chloroallenes in 37−58% yields, reaction with the tertiary arylamines gives the corresponding arylalkynes in 68−77% yields.
创建时间:
2006-09-15



