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Conversion of Propargyl Alcohols to Chloroallenes and Arylalkynes Using the TiCl<sub>4</sub>/R<sub>3</sub>N Reagent System

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NIAID Data Ecosystem2026-03-06 收录
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Whereas the reaction of certain propargyl alcohols with TiCl4 in the presence of tertiary alkylamines gives the corresponding chloroallenes in 37−58% yields, reaction with the tertiary arylamines gives the corresponding arylalkynes in 68−77% yields.

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2006-09-15
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