Materials Data on TcOs3 by Materials Project

TcOs3 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Tc3- is bonded to twelve equivalent Os1+ atoms to form a mixture of face and corner-sharing TcOs12 cuboctahedra. There are six shorter (2.70 Å) and six longer (2.76 Å) Tc–Os bond lengths. Os1+ is bonded in a see-saw-like geometry to four equivalent Tc3- atoms.

TcOs₃结晶于六方晶系P6₃/mmc空间群。该结构为三维结构。Tc³⁻与十二个等价的Os¹⁺原子配位成键，形成兼具面共享与角共享特征的TcOs₁₂立方八面体配位多面体。其中Tc–Os键存在6条较短键长（2.70 Å）与6条较长键长（2.76 Å）。Os¹⁺以跷跷板型配位几何与四个等价的Tc³⁻原子配位成键。