Inorganic acid-catalyzed reaction barrier heights
收藏DataCite Commons2023-05-20 更新2024-08-18 收录
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https://figshare.com/articles/dataset/Inorganic_acid-catalyzed_reaction_barrier_heights/22984118
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资源简介：
The vinyl alcohol-acetaldehyde tautomerization reaction has recently received considerable attention as a potential route for the formation of organic acids in the troposphere (Andrews et al., 2012). We examine the catalytic effect of inorganic acids in the troposphere (e.g., HNO3, H2SO4, and HClO4) on the vinyl alcohol–acetaldehyde tautomerization reaction by means of high-level thermochemical procedures. We show that H2SO4 and HClO4 catalysts lead to near-zero reaction barrier heights for the vinyl alcohol --> acetaldehyde reaction and to low reaction barrier heights in the reverse direction. This work generates a database of accurate inorganic acid-catalyzed reaction barrier heights calculated at the CCSD(T)/CBS level of theory.
提供机构：
figshare
创建时间：
2023-05-20
