Bidentate Ligands Capable of Variable Bond Angles in the Self-Assembly of Discrete Supramolecules
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https://figshare.com/articles/dataset/Bidentate_Ligands_Capable_of_Variable_Bond_Angles_in_the_Self_Assembly_of_Discrete_Supramolecules/3356854
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资源简介:
Flexible donor ligands like 1,2-bis(3-pyridyl)ethyne or 1,4-bis(3-pyridyl)-1,3-butadiyne self-assemble
into discrete supramolecules instead of infinite networks upon combination with organoplatinum
90, 120, and 180 degree acceptor units. These systems are unique examples of versatile pyridine
donors adjusting their bonding directionality to accommodate rigid platinum acceptors in the
formation of closed macrocycles.
创建时间:
2003-12-12



