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K8(K5F)U6Si8O40: An Intergrowth Uranyl Silicate

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Figshare2016-03-29 更新2026-04-29 收录
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https://figshare.com/articles/dataset/K_sub_8_sub_K_sub_5_sub_F_U_sub_6_sub_Si_sub_8_sub_O_sub_40_sub_An_Intergrowth_Uranyl_Silicate/3114235
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Single crystals of K8(K5F)­U6Si8O40 were grown from a mixed alkali halide flux. K8(K5F)­U6Si8O40 is the first intergrowth uranyl silicate, being composed of alternating slabs related to two previously reported uranyl silicates: Cs2USiO6 and [Na9F2]­[(UO2)­(UO2)2(Si2O7)2]. It exhibits intense luminescence, which is influenced by the [(UO2)2O] dimers present in the structure.
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2016-03-29
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