Cation–Cation Interactions between Neptunyl(VI) Units
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https://figshare.com/articles/dataset/Cation_Cation_Interactions_between_Neptunyl_VI_Units/2509543
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The boric acid flux reaction of NpO2(ClO4)2 with NaClO4 affords Na[(NpO2)4B15O24(OH)5(H2O)](ClO4)·0.75H2O (NaNpBO-1). NaNpBO-1 possesses a layered structure consisting of double neptunyl(VI) borate sheets bridged by another NpVI site through cation–cation interactions. The sole presence of NpVI in NaNpBO-1 is supported by absorption and vibrational spectroscopy.
创建时间:
2016-02-20



