Introducing a New Class of N-Phosphoryl Ynamides via Cu(I)-Catalyzed Amidations of Alkynyl Bromides
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https://figshare.com/articles/dataset/Introducing_a_New_Class_of_i_N_i_Phosphoryl_Ynamides_via_Cu_I_Catalyzed_Amidations_of_Alkynyl_Bromides/2613649
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We describe here the first synthesis of N-phosphoryl ynamides featuring C- and P-chirality via copper(I)-catalyzed amidative cross-couplings between phosphoramidates and phosphordiamidates with alkynyl bromides. Also featured is a tandem aza-Claisen–hetero-[2 + 2] cycloaddition for the synthesis of N-phosphoryl azetidin-2-imines.
创建时间:
2016-02-22



