Iron-Catalyzed Dioxygen-Driven C–C Bond Formation: Oxidative Dearomatization of 2‑Naphthols with Construction of a Chiral Quaternary Stereocenter
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Iron_Catalyzed_Dioxygen_Driven_C_C_Bond_Formation_Oxidative_Dearomatization_of_2_Naphthols_with_Construction_of_a_Chiral_Quaternary_Stereocenter/2460727
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资源简介：
Iron(salan) complex 1 was found to catalyze the oxidative dearomatization of 1-substituted 2-naphthols with the formation of an all-carbon quaternary stereocenter in air in the presence of nitroalkanes, to afford the corresponding cyclic enones with high enantioselectivity of 88–96% ee.
创建时间：
2016-02-20
