Cyanide-Bridged Fe(III)−Mn(III) Chain with Metamagnetic Properties and Significant Magnetic Anisotropy
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https://figshare.com/articles/dataset/Cyanide_Bridged_Fe_III_Mn_III_Chain_with_Metamagnetic_Properties_and_Significant_Magnetic_Anisotropy/3029287
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资源简介：
The assembling of [Mn(5-MeOsalen)(H2O)]+ and [(Tp)Fe(CN)3]-
affords the one-dimensional zigzag chain [(Tp)Fe(CN)3Mn(5-MeOsalen)·2CH3OH]n [1; Tp- = hydrotris(pyrazolyl)borate and
5-MeOsalen2- = N,N‘-ethylenebis(5-methoxysalicylideneiminate)].
The corroborated experimental and ab initio data indicate ferromagnetic Fe(III)−Mn(III) couplings and D < 0 anisotropy on Mn(III). The field-induced metamagnetic behavior is due to interchain
effects.
创建时间：
2007-02-05
