Formation of Chlorosilyl Pincer-Type Rhodium Complexes by Multiple Si–H Activations of Bis(phosphine)/Dihydrosilyl Ligands
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Formation_of_Chlorosilyl_Pincer_Type_Rhodium_Complexes_by_Multiple_Si_H_Activations_of_Bis_phosphine_Dihydrosilyl_Ligands/2246434
下载链接
链接失效反馈官方服务：
资源简介：
The synthesis and metalation of two
bis(phosphine)/dihydrosilyl
ligands at rhodium(I) sources is reported. Irrespective of the substitution
at silicon (diaryl versus diamino), multiple Si–H activations
and chloride migration afford tridentate bis(phosphine)/chlorosilyl
complexes of Rh(I). For the diarylsilyl ligand, reaction with a cationic
rhodium(I) triflate precursor gives the analogous triflatosilyl complex.
The [P2Si]H2 proligands and their Rh complexes
provide distinct opportunities for exploring metal/silicon cooperative
reactivity.
创建时间：
2016-02-16
