Two-Dimensional Scaffolds for the Parallel Alignment of Rod-Shaped Conjugated Molecules
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https://figshare.com/articles/dataset/Two_Dimensional_Scaffolds_for_the_Parallel_Alignment_of_Rod_Shaped_Conjugated_Molecules/3032275
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资源简介：
Described is a method for creating two-dimensional, ordered arrays of linear, conjugated organic molecules
on polyimide scaffolds. Key to the design was the enforcement of consecutive 90° twist angles along the
polyimide backbone. Rod molecules that are templated by such scaffolds are held parallel and in the
same plane and have optical properties that are similar to those of monomeric analogues. As supporting
evidence for the structures of the polymers, a series of model compounds were synthesized and
characterized by X-ray crystallography. The polymeric materials are soluble and have been characterized
by 1H NMR, 13C NMR, MALDI-TOF, and UV−vis spectroscopy.
创建时间：
2016-02-29
