Synthesis and Structure of the First Gallium-Bridged Heterodimetallic Complexes, Cp*(dppe)FeGaM(CO)<sub>5</sub> (Cp* = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>, dppe = Ph<sub>2</sub>P(CH<sub>2</sub>)<sub>2</sub>PPh<sub>2</sub>, M = Cr, W)
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
The first Ga-bridged heterodimetallic complexes, Cp*(dppe)FeGaM(CO)5 (Cp* = η5-C5Me5, dppe = Ph2P(CH2)2PPh2, M = Cr (3), W (4)), were synthesized by the reaction of Cp*(dppe)FeGaCl2 and K2[M(CO)5] (M = Cr and W) in THF in 53 and 55% yield, respectively. Crystal structure analysis of 4 revealed that both the Fe−Ga and Ga−W bonds are significantly shorter than the corresponding usual single bonds and comparable to those in gallylene metal complexes.
创建时间：
2016-02-26
