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Boronate Ester Bullvalenes

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Figshare2020-02-11 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Boronate_Ester_Bullvalenes/11842692
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Boronate ester bullvalenes are now accessible in two to four operationally simple steps. This unlocks late-stage diversification through Suzuki cross-coupling reactions to give mono-, di-, and trisubstituted bullvalenes. Moreover, a linchpin strategy enables preprogrammed installation of two different substituents. Analysis of solution phase isomer distributions and single-crystal X-ray structures reveals that isomer preference in the crystal lattice is due to general shape selectivity.
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2020-02-11
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